Three-Dimensional Microscaffolds Exhibiting Spatially Resolved Surface Chemistry

  • chair:

    Richter, B. / Pauloehrl, T. / Kaschke, J. / Fichtner, D. / Fischer, J. / Greiner, A. / Wedlich, D. / Wegener, M. / Delaittre, G. / Barner-Kowollik, C. / Bastmeyer, M. (2013)
  • place:

    Advanced Materials 25 (2013), 42, 6117-6122
  • Date: 2013

  • Richter, B. / Pauloehrl, T. / Kaschke, J. / Fichtner, D. / Fischer, J. / Greiner, A. / Wedlich, D. / Wegener, M. / Delaittre, G. / Barner-Kowollik, C. / Bastmeyer, M. (2013): „Three-Dimensional Microscaffolds Exhibiting Spatially Resolved Surface Chemistry“. In: Advanced Materials 25 (2013), 42, 6117-6122

Abstract

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Spatial control over the surface chemistry of 3D organic–inorganic hybrid microscaffolds is achieved by a two-photon-triggered cycloaddition. Following a coating step with photoactivatable dienes via silanization, surface irradiation with a femtosecond-pulsed laser in the presence of functional dienophiles enables a site-selective alteration of the surface chemistry. Bioconjugation with fluorescent protein tags is employed to reveal the 3D molecular patterns.