Enantiopure Metal-Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption

  • chair:

    Liu, B. / Shekhah, O. / Arslan, H. / Liu, J. / Wöll, C. / Fischer, R. (2012)
  • place:

    Angewandte Chemie 3 (2012), 51, 807-810
  • Date: 2012

  • Liu, B. / Shekhah, O. / Arslan, H. / Liu, J. / Wöll, C. / Fischer, R. (2012): „Enantiopure Metal-Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption“. In: Angewandte Chemie 3 (2012), 51, 807-810

Abstract

Preferred (110) and (001) orientation of enantiopure [{Zn2((+)cam)2(dabco)}n] ((+)cam=(1R,3S)-(+)-camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal–organic frameworks (SURMOF) [Zn2((±)cam)2(dabco)] pairs can be demonstrated.

 

 

 

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