Modulating the photolysis of aryl azides in a supramolecular host to develop photoactivatable fluorophores
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chair:
Qiu, X. / Pohl, E. / Jung, A. /Cai, Q. / Su, H. / Fuhr, O. / Schepers, U. / Bräse, S. (2024)
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place:
Chemical Communications, 88, 2024
- Date: Oktober 2024
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Abstract
Photolysis of aryl azides is a convenient method to approach more functionalized systems in chemical biology. Here, we present a set of photoactivatable aryl azides that undergo controlled reaction pathways within the cucurbit[7]uril (CB7) cavity upon photolysis. The fluorescence turn-on process is utilized for bioimaging.