Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3 terminated self assembled monolayers on Au(111)

  • chair:

    Hermes, S. / Schröder, F. / Chelmowski, R. / Wöll, Ch. / Fischer, R. A. (2005)
  • place: J. Am. Chem. Soc. 127 (2005),40 13744-13745

  • Date: 2005

  • Hermes, S. / Schröder, F. / Chelmowski, R. / Wöll, Ch. / Fischer, R. A. (2005): „Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3 terminated self assembled monolayers on Au(111)“. In: J. Am. Chem. Soc. 127 (2005),40 13744-13745

Abstract

Metal−Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.


 

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